The Spain football team beat the defending champions Soviet Union 2-1 in the final held at the Santiago Bernabeu, the home of Real Madrid.
This was the first UEFA Euro final to go into a penalty shootout.
Mbappe, Antoine Griezmann and Karim Benzema are poised to headline one of the most potent attacks in the entire tournament.
He put the ball in from close range after a right-wing corner was flicked on to Marco Verratti, whose stooping header was tipped onto the post by goalkeeper Jordan Pickford.
The 2014 World Cup winner will not see Die Mannschaft to the end of the process however, having announced that he will step down after Euro 2020.
Storylines Though World Cup qualifying groups have in the past been known to throw up the odd group of death -- take 2018 when Italy were drawn alongside Spain and found themselves knocked out by Sweden in the playoffs -- this year there is no obvious clash between two footballing juggernauts.